Description
The most commonly used working electrode materials are platinum, gold, carbon, and mercury. Among these, platinum is likely the favorite, demonstrating good electrochemical inertness and ease of fabrication into many forms. The biggest disadvantage to the use of platinum, other than its high cost, is that the presence of even small amounts of water or acid in the electrolyte leads to the reduction of hydrogen ion to form hydrogen gas (hydrogen evolution) at fairly modest negative potentials (E = -0.059 x pH). This reduction obscures any useful analytical signal.
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